CHEMICAL ANALYSIS OF EARLY U. S. SILVER COINS

Most numismatists will agree that the single most important Mint related legislation in our nation's history was the Mint and Coinage Act of April 2, 1792. In addition toestablishing the first Mint of the United States, one of the key aspects of this law was Congress's mandate for the composition of the silver coins. Per Section 13:

The law specified that silver coins were to contain 1485 parts of silver and 179 parts copper alloy. This equated to a standard of 1485 / 1664 or 89.24278% or89.24+% pure silver, and 10.75722% or 10.76-% copper alloy.

Multiple documents stored within the National Archives and Records Administration (NARA) and the Library of Congress indicate that under the leadership of Mint Directors DavidRittenhouse and Henry William de Saussure, some or all of the 1794, and most or all of the 1795 dated silver coins were produced to a 90% silver and 10% copper standard. Then,effective November 6, 1795, under the leadership of its third Director, Elias Boudinot, the Mint reverted to the 89.24+% silver and 10.76-% copper standard.

The first phase of a multi-phase project was just completed to determine:

1. what elements and percentages are in the silver coins of 1794 and 1795,

2. what elements and percentages are in the copper coins of 1794 and 1795,

3. whether the Mint attempted to refine any of the silver bullion deposits made during 1794 and 1795 to a standard of 89.24+% silver and 10.76-% copper as per the Mint andCoinage Act of April 2, 1792,

4. whether the Mint attempted to refine any of the silver bullion deposits made during 1794 and 1795 to a standard of 90% silver and 10% copper, thus violating the Mint andCoinage Act of April 2, 1792,

5. whether Mint personnel were capable of achieving a refining target of 89.24+% silver and 10.76-% copper,

6. whether Mint personnel were capable of achieving a refining target of 90% silver and 10% copper,

7. the technologies available to 18th century precious metal refiners, and

8. the Mint's practices for refining silver bullion deposits.

This project began in March, 2015. Thanks to support from the Eric P. Newman Numismatic Education Society, Heritage Auctions, and the Terry Brand Estate, modern chemicalanalysis technologies were used to determine the chemical compositions of 1794 and 1795 silver and copper coins. Based on the compositional results, statistical analyses wereperformed, and preliminary conclusions were made.

To read the complete article, see:

Chemical Analysis of 1794 & 1795 U. S. Silver Coins - Part 1 (https://nnp.wustl.edu/library/book/554528)

Before and after pictures of a 1795 O-105 Half Dollar. The center piece in the after picture was sent for ICP-AES analysis.

To read the complete article, see:

RESEARCHERS PUT EARLY SILVER COINS TO NEW TESTS (http://www.coinbooks.org/v21/esylum_v21n33a12.html)